TY - JOUR
T1 - Synthesis and reactivity of 5,10,15-triaryl doubly N-confused bilanes
AU - Toganoh, Motoki
AU - Gokulnath, Sabapathi
AU - Kawabe, Yasunori
AU - Furuta, Hiroyuki
PY - 2012/4/2
Y1 - 2012/4/2
N2 - A series of 5,10,15-tris(pentafluorophenyl) doubly N-confused bilanes were synthesized in a stepwise manner with the aid of sterically demanding N-protecting groups, in which the difference in reactivity between regular pyrrole and N-confused pyrrole plays a crucial role in the synthetic strategy. Some doubly N-confused bilanes were converted into porphyrinoids or a unique 2:2 copper(II) complex with a helical structure. In addition, the conformations and electronic states of the doubly N-confused bilanes were investigated theoretically, giving fruitful information about the effect of confusion on the bilane skeleton.
AB - A series of 5,10,15-tris(pentafluorophenyl) doubly N-confused bilanes were synthesized in a stepwise manner with the aid of sterically demanding N-protecting groups, in which the difference in reactivity between regular pyrrole and N-confused pyrrole plays a crucial role in the synthetic strategy. Some doubly N-confused bilanes were converted into porphyrinoids or a unique 2:2 copper(II) complex with a helical structure. In addition, the conformations and electronic states of the doubly N-confused bilanes were investigated theoretically, giving fruitful information about the effect of confusion on the bilane skeleton.
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U2 - 10.1002/chem.201103034
DO - 10.1002/chem.201103034
M3 - Article
C2 - 22362658
AN - SCOPUS:84859336768
SN - 0947-6539
VL - 18
SP - 4380
EP - 4391
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 14
ER -