Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety

Takahiro Matsumoto, Koji Yoshimoto, Chunbai Zheng, Yasuhito Shomura, Yoshiki Higuchi, Hidetaka Nakai, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    We report the synthesis, characterization, and reactivity of a NiRu monohydride complex with a pyridine-bound hexamethylbenzene ligand. We investigate the mechanistic insights it provides on the H2-activation of [NiFe]hydrogenase.

    Original languageEnglish
    Pages (from-to)197-199
    Number of pages3
    JournalChemistry Letters
    Volume45
    Issue number2
    DOIs
    Publication statusPublished - 2016

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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