Synthesis and reactivity of bucky ruthenocene Ru(η5-C 60Me5)(η5-C5H5)

Yutaka Matsuo, Yoichiro Kuninobu, Shingo Ito, Eiichi Nakamura

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Metathetical coupling of an η5-fullerene ruthenium complex Ru(η5-C60Me5)Cl(CO)2 and sodium cyclopentadienide gives a molecular hybrid of ruthenocene and fullerene, Ru(η5-C60Me5)(η5-C 5H5) (bucky ruthenocene), the structure of which was determined by spectroscopic and crystallographic analyses. The molecule shows unique reactivity among known ferrocene and ruthenocene compounds.

Original languageEnglish
Pages (from-to)68-69
Number of pages2
JournalChemistry Letters
Volume33
Issue number1
DOIs
Publication statusPublished - Jan 5 2004
Externally publishedYes

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Fullerenes
Ruthenium
Carbon Monoxide
Sodium
Molecules
ruthenocene
ferrocene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis and reactivity of bucky ruthenocene Ru(η5-C 60Me5)(η5-C5H5). / Matsuo, Yutaka; Kuninobu, Yoichiro; Ito, Shingo; Nakamura, Eiichi.

In: Chemistry Letters, Vol. 33, No. 1, 05.01.2004, p. 68-69.

Research output: Contribution to journalArticle

Matsuo, Yutaka ; Kuninobu, Yoichiro ; Ito, Shingo ; Nakamura, Eiichi. / Synthesis and reactivity of bucky ruthenocene Ru(η5-C 60Me5)(η5-C5H5). In: Chemistry Letters. 2004 ; Vol. 33, No. 1. pp. 68-69.
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