@article{5addb216506d425692b8b37bf4f4a446,
title = "Synthesis and Reactivity of Cobalt-Dinitrogen Complexes Bearing Anionic PCP-Type Pincer Ligands toward Catalytic Silylamine Formation from Dinitrogen",
abstract = "A series of cobalt(I)-dinitrogen complexes bearing anionic 4-substituted benzene-based PCP-type pincer ligands are synthesized and characterized. These complexes work as highly efficient catalysts for the formation of silylamine from dinitrogen under ambient reaction conditions to produce up to 371 equiv of silylamine based on the cobalt atom of the catalyst. ",
author = "Shogo Kuriyama and Shenglan Wei and Hiromasa Tanaka and Asuka Konomi and Kazunari Yoshizawa and Yoshiaki Nishibayashi",
note = "Funding Information: The present project is supported by CREST, JST (Grant JPMJCR1541). We acknowledge Grants-in-Aid for Scientific Research (Grants JP20H05671, JP20K21203, and JP20K15295) from JSPS and MEXT. Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",
year = "2022",
doi = "10.1021/acs.inorgchem.2c00234",
language = "English",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
}