Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Yoshiya Sekiguchi, Fanqiang Meng, Hiromasa Tanaka, Aya Eizawa, Kazuya Arashiba, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

Original languageEnglish
Pages (from-to)11322-11326
Number of pages5
JournalDalton Transactions
Volume47
Issue number33
DOIs
Publication statusPublished - Jan 1 2018

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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