Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Yoshiya Sekiguchi, Fanqiang Meng, Hiromasa Tanaka, Aya Eizawa, Kazuya Arashiba, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

Original languageEnglish
Pages (from-to)11322-11326
Number of pages5
JournalDalton Transactions
Volume47
Issue number33
DOIs
Publication statusPublished - Jan 1 2018

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hydrazine
Bearings (structural)
Pyrroles
X ray analysis
Titanium
Ammonia
Catalyst activity
Nitrogen
Gases
Ligands

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Sekiguchi, Y., Meng, F., Tanaka, H., Eizawa, A., Arashiba, K., Nakajima, K., ... Nishibayashi, Y. (2018). Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands. Dalton Transactions, 47(33), 11322-11326. https://doi.org/10.1039/c8dt02739k

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands. / Sekiguchi, Yoshiya; Meng, Fanqiang; Tanaka, Hiromasa; Eizawa, Aya; Arashiba, Kazuya; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

In: Dalton Transactions, Vol. 47, No. 33, 01.01.2018, p. 11322-11326.

Research output: Contribution to journalArticle

Sekiguchi, Y, Meng, F, Tanaka, H, Eizawa, A, Arashiba, K, Nakajima, K, Yoshizawa, K & Nishibayashi, Y 2018, 'Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands', Dalton Transactions, vol. 47, no. 33, pp. 11322-11326. https://doi.org/10.1039/c8dt02739k
Sekiguchi, Yoshiya ; Meng, Fanqiang ; Tanaka, Hiromasa ; Eizawa, Aya ; Arashiba, Kazuya ; Nakajima, Kazunari ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands. In: Dalton Transactions. 2018 ; Vol. 47, No. 33. pp. 11322-11326.
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