Abstract
Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.
| Original language | English |
|---|---|
| Pages (from-to) | 1949-1951 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 42 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Mar 4 2001 |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry
Cite this
Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units. / Shimakoshi, Hisashi; Goto, Akihiro; Tachi, Yoshimitsu; Naruta, Yoshinori; Hisaeda, Yoshio.
In: Tetrahedron Letters, Vol. 42, No. 10, 04.03.2001, p. 1949-1951.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units
AU - Shimakoshi, Hisashi
AU - Goto, Akihiro
AU - Tachi, Yoshimitsu
AU - Naruta, Yoshinori
AU - Hisaeda, Yoshio
PY - 2001/3/4
Y1 - 2001/3/4
N2 - Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.
AB - Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.
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UR - http://www.scopus.com/inward/citedby.url?scp=0035804505&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(01)00040-5
DO - 10.1016/S0040-4039(01)00040-5
M3 - Article
VL - 42
SP - 1949
EP - 1951
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 10
ER -