Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

Hisashi Shimakoshi, Akihiro Goto, Yoshimitsu Tachi, Yoshinori Naruta, Yoshio Hisaeda

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Abstract

Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.

Original languageEnglish
Pages (from-to)1949-1951
Number of pages3
JournalTetrahedron Letters
Volume42
Issue number10
DOIs
Publication statusPublished - Mar 4 2001

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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