Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

Hisashi Shimakoshi; Akihiro Goto; Yoshimitsu Tachi; Yoshinori Naruta; Yoshio Hisaeda

doi:10.1016/S0040-4039(01)00040-5

Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

Hisashi Shimakoshi, Akihiro Goto, Yoshimitsu Tachi, Yoshinori Naruta, Yoshio Hisaeda

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.

Original language	English
Pages (from-to)	1949-1951
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4039(01)00040-5
Publication status	Published - Mar 4 2001

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(01)00040-5

Cite this

@article{1f0f12bb3eb64a2e9782568dbd3951d7,

title = "Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units",

abstract = "Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.",

author = "Hisashi Shimakoshi and Akihiro Goto and Yoshimitsu Tachi and Yoshinori Naruta and Yoshio Hisaeda",

year = "2001",

month = mar,

day = "4",

doi = "10.1016/S0040-4039(01)00040-5",

language = "English",

volume = "42",

pages = "1949--1951",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "10",

}

TY - JOUR

T1 - Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

AU - Shimakoshi, Hisashi

AU - Goto, Akihiro

AU - Tachi, Yoshimitsu

AU - Naruta, Yoshinori

AU - Hisaeda, Yoshio

PY - 2001/3/4

Y1 - 2001/3/4

N2 - Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.

AB - Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.

UR - http://www.scopus.com/inward/record.url?scp=0035804505&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035804505&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(01)00040-5

DO - 10.1016/S0040-4039(01)00040-5

M3 - Article

AN - SCOPUS:0035804505

VL - 42

SP - 1949

EP - 1951

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 10

ER -

Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this