Synthesis and redox behavior of dialkylated dicobalt complexes having two discrete salen units

Hisashi Shimakoshi, Akihiro Goto, Yoshimitsu Tachi, Yoshinori Naruta, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    15 Citations (Scopus)

    Abstract

    Novel dialkylated dicobalt complexes with two discrete salen units have been synthesized and characterized by UV-vis, NMR, and ESI-mass spectroscopies as well as elemental analyses. Redox behavior of the complexes was investigated by means of cyclic voltammetry and ESR spin-trapping techniques. The results indicate that cobalt-carbon bonds cleave homolytically to produce the radical species during the electrolysis.

    Original languageEnglish
    Pages (from-to)1949-1951
    Number of pages3
    JournalTetrahedron Letters
    Volume42
    Issue number10
    DOIs
    Publication statusPublished - Mar 4 2001

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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