Synthesis and stereochemical behavior of (E)-cyclononene derivatives

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Abstract

A versatile synthetic approach to planar chiral molecules from (E)-5-cyclononen-1-one (1) has been developed; these molecules have multifunctionalities with (E)-cyclononene skeleton. The newly synthesized keto-ester 3 having central chirality shows labile planar chirality. In contrast, enol derivative 4 and enyne 5 show robust planar chirality.

Original languageEnglish
Pages (from-to)591-593
Number of pages3
JournalChemistry Letters
Volume40
Issue number6
DOIs
Publication statusPublished - May 27 2011

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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