Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa, Junnai Ikadai, Akinobu Naka, Joji Ohshita, Atsutaka Kunai, Kazunari Yoshizawa, Song Yun Kang, Tokio Yamabe

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

Original languageEnglish
Pages (from-to)1059-1061
Number of pages3
JournalOrganometallics
Volume20
Issue number6
DOIs
Publication statusPublished - Mar 19 2001
Externally publishedYes

Fingerprint

Siloxanes
Stereochemistry
stereochemistry
Palladium
Oxygen
siloxanes
dienes
synthesis
palladium
oxygen
phenylacetylene
azobis(isobutyronitrile)

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene. / Ishikawa, Mitsuo; Ikadai, Junnai; Naka, Akinobu; Ohshita, Joji; Kunai, Atsutaka; Yoshizawa, Kazunari; Kang, Song Yun; Yamabe, Tokio.

In: Organometallics, Vol. 20, No. 6, 19.03.2001, p. 1059-1061.

Research output: Contribution to journalArticle

Ishikawa, M, Ikadai, J, Naka, A, Ohshita, J, Kunai, A, Yoshizawa, K, Kang, SY & Yamabe, T 2001, 'Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene', Organometallics, vol. 20, no. 6, pp. 1059-1061. https://doi.org/10.1021/om000909q
Ishikawa, Mitsuo ; Ikadai, Junnai ; Naka, Akinobu ; Ohshita, Joji ; Kunai, Atsutaka ; Yoshizawa, Kazunari ; Kang, Song Yun ; Yamabe, Tokio. / Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene. In: Organometallics. 2001 ; Vol. 20, No. 6. pp. 1059-1061.
@article{074ad0dc6ff14050ba98bf73c22fe975,
title = "Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene",
abstract = "The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.",
author = "Mitsuo Ishikawa and Junnai Ikadai and Akinobu Naka and Joji Ohshita and Atsutaka Kunai and Kazunari Yoshizawa and Kang, {Song Yun} and Tokio Yamabe",
year = "2001",
month = "3",
day = "19",
doi = "10.1021/om000909q",
language = "English",
volume = "20",
pages = "1059--1061",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "6",

}

TY - JOUR

T1 - Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

AU - Ishikawa, Mitsuo

AU - Ikadai, Junnai

AU - Naka, Akinobu

AU - Ohshita, Joji

AU - Kunai, Atsutaka

AU - Yoshizawa, Kazunari

AU - Kang, Song Yun

AU - Yamabe, Tokio

PY - 2001/3/19

Y1 - 2001/3/19

N2 - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

AB - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

UR - http://www.scopus.com/inward/record.url?scp=0035911990&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035911990&partnerID=8YFLogxK

U2 - 10.1021/om000909q

DO - 10.1021/om000909q

M3 - Article

AN - SCOPUS:0035911990

VL - 20

SP - 1059

EP - 1061

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 6

ER -