Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa, Junnai Ikadai, Akinobu Naka, Joji Ohshita, Atsutaka Kunai, Kazunari Yoshizawa, Song Yun Kang, Tokio Yamabe

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

Original languageEnglish
Pages (from-to)1059-1061
Number of pages3
JournalOrganometallics
Volume20
Issue number6
DOIs
Publication statusPublished - Mar 19 2001
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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