Synthesis and structure of a water-soluble μ-η1: η1-N2 dinuclear RuII complex with a polyamine ligand

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Andrew Robertson, Hidetaka Nakai, Hiromasa Tanaka, Takashi Kamachi, Yoshihito Shiota, Kazunari Yoshizawa, Koichiro Asazawa, Hirohisa Tanaka, Seiji Ogo

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Abstract

We report the first example of a μ-η11-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

Original languageEnglish
Pages (from-to)149-151
Number of pages3
JournalChemistry Letters
Volume45
Issue number2
DOIs
Publication statusPublished - Jan 1 2016

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X ray analysis
Polyamines
Stretching
Raman spectroscopy
Chemical activation
Ligands
Water

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis and structure of a water-soluble μ-η1 : η1-N2 dinuclear RuII complex with a polyamine ligand. / Yoshimoto, Koji; Yatabe, Takeshi; Matsumoto, Takahiro; Robertson, Andrew; Nakai, Hidetaka; Tanaka, Hiromasa; Kamachi, Takashi; Shiota, Yoshihito; Yoshizawa, Kazunari; Asazawa, Koichiro; Tanaka, Hirohisa; Ogo, Seiji.

In: Chemistry Letters, Vol. 45, No. 2, 01.01.2016, p. 149-151.

Research output: Contribution to journalArticle

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AU - Nakai, Hidetaka

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AU - Ogo, Seiji

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