Abstract
A new ternary nitride, SrTiN2, has been synthesized by the solid-state reaction of Sr2N with TiN and characterized by powder X-ray diffraction. SrTiN2 crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO2. Titanium is coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layers and is coordinated to five nitrogen atoms. The title compound is only the third example of a ternary titanium nitride.
| Original language | English |
|---|---|
| Pages (from-to) | 3775-3778 |
| Number of pages | 4 |
| Journal | Inorganic chemistry |
| Volume | 37 |
| Issue number | 15 |
| Publication status | Published - Jul 27 1998 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Gregory, D. H., Barker, M. G., Edwards, P. P., & Siddons, D. J. (1998). Synthesis and Structure of the New Ternary Nitride SrTiN2. Inorganic chemistry, 37(15), 3775-3778.