Synthesis and Structure of the New Ternary Nitride SrTiN2

D. H. Gregory, M. G. Barker, P. P. Edwards, D. J. Siddons

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22 Citations (Scopus)

Abstract

A new ternary nitride, SrTiN2, has been synthesized by the solid-state reaction of Sr2N with TiN and characterized by powder X-ray diffraction. SrTiN2 crystallizes in the tetragonal space group P4/nmm (a = 3.8799(2) Å, c = 7.6985(4) Å, Z = 2) and is isostructural with KCoO2. Titanium is coordinated to five nitrogens in a distorted square-based pyramidal geometry, forming layers of edge-sharing pyramids which stack along the (001) direction. Strontium is situated between the Ti-N layers and is coordinated to five nitrogen atoms. The title compound is only the third example of a ternary titanium nitride.

Original languageEnglish
Pages (from-to)3775-3778
Number of pages4
JournalInorganic chemistry
Volume37
Issue number15
Publication statusPublished - Jul 27 1998
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Gregory, D. H., Barker, M. G., Edwards, P. P., & Siddons, D. J. (1998). Synthesis and Structure of the New Ternary Nitride SrTiN2. Inorganic chemistry, 37(15), 3775-3778.