Synthesis and structures of novel discrete Ni(II)-Ln(III) heterodinuclear complexes (Ln = Gd or Lu)

Nobuyuki Kondoh, Yuko Shimizu, Masato Kurihara, Hiroshi Sakiyama, Masatomi Sakamoto, Yuzo Nishida, Yoshihiko Sadaoka, Masaaki Ohba, Hisashi Okawa

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The first discrete NiLn heteronuclear complexes, [Ni(salabza)Ln(hfac)3] (Ln = Gd(III) and Lu(III)), were synthesized, where H2salabza and Hhfac denote N,N′-bis(salicy-lidene)-2-aminobenzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analyses revealed that the Ni(II) and Ln(III) ions are bridged by the two phenolate oxygen atoms of salabza2- and that the shortest intermolecular separation is > 5.9 Å for the Ni-Ni distance, indicating that the present complexes consist of a discrete dinuclear NiLn unit.

Original languageEnglish
Pages (from-to)1007-1008
Number of pages2
JournalBulletin of the Chemical Society of Japan
Volume76
Issue number5
DOIs
Publication statusPublished - Jan 1 2003

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Kondoh, N., Shimizu, Y., Kurihara, M., Sakiyama, H., Sakamoto, M., Nishida, Y., ... Okawa, H. (2003). Synthesis and structures of novel discrete Ni(II)-Ln(III) heterodinuclear complexes (Ln = Gd or Lu). Bulletin of the Chemical Society of Japan, 76(5), 1007-1008. https://doi.org/10.1246/bcsj.76.1007