Synthesis of 2-aminomethylpyridene-appended [60]fullerenes. On the difference in the metal-binding properties between 5,6-open and 6,6-closed isomers

Atsushi Ikeda, Chie Fukuhara, Seiji Shinkai

Research output: Contribution to journalArticle

Abstract

Two 2-aminomethylpyridine-appended [60]fullerenes (1) with the 5,6-open and the 6,6-closed structure were synthesized in order to examine the influence of the structural difference on the metal-binding ability. Both compounds could form the 1:1 complex with Ag+ but the Kass for 5,6-1 was larger by more than two orders of magnitude than that for 6,6-1.

Original languageEnglish
Pages (from-to)915-916
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - Jan 1 1998

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Isomers
Metals
fullerene C60

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis of 2-aminomethylpyridene-appended [60]fullerenes. On the difference in the metal-binding properties between 5,6-open and 6,6-closed isomers. / Ikeda, Atsushi; Fukuhara, Chie; Shinkai, Seiji.

In: Chemistry Letters, No. 9, 01.01.1998, p. 915-916.

Research output: Contribution to journalArticle

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