TY - JOUR
T1 - Synthesis of 2-Iodoazulenes by the Iododeboronation of Azulen-2-ylboronic Acid Pinacol Esters with Copper(I) Iodide
AU - Narita, Masahiro
AU - Murafuji, Toshihiro
AU - Yamashita, Saki
AU - Fujinaga, Masayuki
AU - Hiyama, Kumiko
AU - Oka, Yurie
AU - Tani, Fumito
AU - Kamijo, Shin
AU - Ishiguro, Katsuya
N1 - Funding Information:
This work was supported by JSPS KAKENHI Grant no. 16K05697 to T.M. We are grateful to the Center of Instrumental Analysis, Yamaguchi University. This work was performed under the Cooperative Research Program of “Network Joint Research Center for Materials and Devices” (Institute for Materials Chemistry and Engineering, Kyushu University).
Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/2/2
Y1 - 2018/2/2
N2 - Azulen-2-ylboronic acid pinacol ester, prepared by iridium-catalyzed C-H borylation of azulene, efficiently underwent iododeboronation with a stoichiometric amount of copper(I) iodide. This reaction allowed the synthesis of 2-iodoazulene in only two steps starting from azulene. This methodology was successfully applied to analogous azulenes.
AB - Azulen-2-ylboronic acid pinacol ester, prepared by iridium-catalyzed C-H borylation of azulene, efficiently underwent iododeboronation with a stoichiometric amount of copper(I) iodide. This reaction allowed the synthesis of 2-iodoazulene in only two steps starting from azulene. This methodology was successfully applied to analogous azulenes.
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U2 - 10.1021/acs.joc.7b02820
DO - 10.1021/acs.joc.7b02820
M3 - Article
C2 - 29300095
AN - SCOPUS:85041573205
VL - 83
SP - 1298
EP - 1303
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 3
ER -