Synthesis of a biotemplated lithium ion-sieve derived from fungally formed birnessite

Keiko Sasaki, Qianqian Yu

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Citation (Scopus)

Abstract

Biogenic birnessite is a stable form of manganese oxide found in nature that originates from microbial oxidation. Its unique structural properties provide potential for materials scientists to fabricate new functionalized materials. This study used a manganese-oxidizing fungus, Paraconiothyrium sp. WL-2, as a bio-oxidizer and biotemplate to prepare a lithium ion-sieve in the shape of a microtube through a solid-state transformation by calcination. The effect of calcination temperature was studied in terms of chemical composition, structure, and morphology. The results showed that the calcination temperature affects not only the weight fraction but also the crystallinity of the lithium manganese oxide spinel, which significantly influences the adsorption capacity of lithium ions.

Original languageEnglish
Title of host publicationAdvances in the Environmental Biogeochemistry of Manganese Oxides
EditorsWei Li, Xionghan Feng, Donald L. Sparks, Mengqiang Zhu
PublisherAmerican Chemical Society
Pages169-183
Number of pages15
DOIs
Publication statusPublished - Jan 1 2015

Publication series

NameACS Symposium Series
Volume1197
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Sasaki, K., & Yu, Q. (2015). Synthesis of a biotemplated lithium ion-sieve derived from fungally formed birnessite. In W. Li, X. Feng, D. L. Sparks, & M. Zhu (Eds.), Advances in the Environmental Biogeochemistry of Manganese Oxides (pp. 169-183). (ACS Symposium Series; Vol. 1197). American Chemical Society. https://doi.org/10.1021/bk-2015-1197.ch009