Synthesis of a phosphorus-containing hybrid porphyrin

Yoshihiro Matano, Takashi Nakabuchi, Tooru Miyajima, Hiroshi Imahori, Haruyuki Nakano

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

(Diagram presented) A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between σ4-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl] thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the σ3-P,N 2,S-hybrid porphyrin exhibits high aromaticity as an 18π-electron system in terms of both geometric and magnetic criteria.

Original languageEnglish
Pages (from-to)5713-5716
Number of pages4
JournalOrganic Letters
Volume8
Issue number25
DOIs
Publication statusPublished - Dec 7 2006

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Porphyrins
porphyrins
Phosphorus
phosphorus
Thiophenes
synthesis
thiophenes
Discrete Fourier transforms
Absorption spectra
Condensation
condensation
diagrams
Nuclear magnetic resonance
Electrons
absorption spectra
nuclear magnetic resonance
electrons

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Matano, Y., Nakabuchi, T., Miyajima, T., Imahori, H., & Nakano, H. (2006). Synthesis of a phosphorus-containing hybrid porphyrin. Organic Letters, 8(25), 5713-5716. https://doi.org/10.1021/ol0622763

Synthesis of a phosphorus-containing hybrid porphyrin. / Matano, Yoshihiro; Nakabuchi, Takashi; Miyajima, Tooru; Imahori, Hiroshi; Nakano, Haruyuki.

In: Organic Letters, Vol. 8, No. 25, 07.12.2006, p. 5713-5716.

Research output: Contribution to journalArticle

Matano, Y, Nakabuchi, T, Miyajima, T, Imahori, H & Nakano, H 2006, 'Synthesis of a phosphorus-containing hybrid porphyrin', Organic Letters, vol. 8, no. 25, pp. 5713-5716. https://doi.org/10.1021/ol0622763
Matano Y, Nakabuchi T, Miyajima T, Imahori H, Nakano H. Synthesis of a phosphorus-containing hybrid porphyrin. Organic Letters. 2006 Dec 7;8(25):5713-5716. https://doi.org/10.1021/ol0622763
Matano, Yoshihiro ; Nakabuchi, Takashi ; Miyajima, Tooru ; Imahori, Hiroshi ; Nakano, Haruyuki. / Synthesis of a phosphorus-containing hybrid porphyrin. In: Organic Letters. 2006 ; Vol. 8, No. 25. pp. 5713-5716.
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