Synthesis of a phosphorus-containing hybrid porphyrin

Yoshihiro Matano, Takashi Nakabuchi, Tooru Miyajima, Hiroshi Imahori, Haruyuki Nakano

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Abstract

(Diagram presented) A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between σ4-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl] thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the σ3-P,N 2,S-hybrid porphyrin exhibits high aromaticity as an 18π-electron system in terms of both geometric and magnetic criteria.

Original languageEnglish
Pages (from-to)5713-5716
Number of pages4
JournalOrganic Letters
Volume8
Issue number25
DOIs
Publication statusPublished - Dec 7 2006

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Matano, Y., Nakabuchi, T., Miyajima, T., Imahori, H., & Nakano, H. (2006). Synthesis of a phosphorus-containing hybrid porphyrin. Organic Letters, 8(25), 5713-5716. https://doi.org/10.1021/ol0622763