Synthesis of acetic acid from CO2, CH3I and H2using a water-soluble electron storage catalyst

Takeshi Yatabe, Kazuki Kamitakahara, Kaede Higashijima, Tatsuya Ando, Takahiro Matsumoto, Ki Seok Yoon, Takao Enomoto, Seiji Ogo

Research output: Contribution to journalArticlepeer-review

Abstract

This paper reports a possible mechanism of acetic acid formation from CO2, CH3I and H2in aqueous media and the central role played by a water-soluble Rh-based electron storage catalyst. In addition to water-solubility, we also report the crystal structures of two presumed intermediates. These findings together reveal (1) the advantage of water, not only as a green solvent, but also as a reactive Lewis base to extract H+from H2, (2) the role of the metal (Rh) centre as a point for storing electrons from H2and (3) the importance of an electron-withdrawing ligand (quaterpyridine, qpy) that supports electron storage.

Original languageEnglish
Pages (from-to)4772-4774
Number of pages3
JournalChemical Communications
Volume57
Issue number39
DOIs
Publication statusPublished - May 14 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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