Synthesis of an anthraquinone-bridged bis(terpyridine) ligand and its use in the stepwise fabrication of complex oligomer wires on gold

Mitsuya Utsuno, Fumiyuki Toshimitsu, Shoko Kume, Hiroshi Nishihara

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

A new bis(terpyridine) ligand with an anthraquinone linker was synthesized. Stepwise coordination reactions at the gold surface using this ligand gave homo-metal oligomer wires up to pentamer, [nFeL1] (n = 1-5), and hetero-metal oligomer wires with ferrocene as the terminal group, [1FeL 11FeL2Fc]. Electrochemical properties of these modified electrodes were examined.

Original languageEnglish
Pages (from-to)153-160
Number of pages8
JournalMacromolecular Symposia
Volume270
Issue number1
DOIs
Publication statusPublished - Aug 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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