Synthesis of and amine recognition with a Cu(II)-bridged biscalix[4]arene

Kiyoshi Fujimoto, Seiji Shinkai

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

A biscalix[4]arene (7) in which the upper rims are linked by two Cu(II)-chelate complexes has been synthesized. This is a novel method for the synthesis of biscalix[4]arenes using the self-association nature of metal ligands. Compound 7 recognized diamine substrates using a cavity composed of two Cu(II)-chelate complexes.

Original languageEnglish
Pages (from-to)2915-2918
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number18
DOIs
Publication statusPublished - May 2 1994

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Diamines
Amines
Metals
Association reactions
Ligands
Substrates

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Synthesis of and amine recognition with a Cu(II)-bridged biscalix[4]arene. / Fujimoto, Kiyoshi; Shinkai, Seiji.

In: Tetrahedron Letters, Vol. 35, No. 18, 02.05.1994, p. 2915-2918.

Research output: Contribution to journalArticle

Fujimoto, Kiyoshi ; Shinkai, Seiji. / Synthesis of and amine recognition with a Cu(II)-bridged biscalix[4]arene. In: Tetrahedron Letters. 1994 ; Vol. 35, No. 18. pp. 2915-2918.
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