Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe, Takahiro Kikunaga, Takahiro Matsumoto, Hidetaka Nakai, Ki Seok Yoon, Seiji Ogo

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

Original languageEnglish
Pages (from-to)1380-1382
Number of pages3
JournalChemistry Letters
Volume43
Issue number8
DOIs
Publication statusPublished - Jan 1 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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