Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe; Takahiro Kikunaga; Takahiro Matsumoto; Hidetaka Nakai; Ki Seok Yoon; Seiji Ogo

doi:10.1246/cl.140376

Synthesis of aqueous-stable and water-soluble mononuclear nonheme Mn^V-Oxo complexes using H₂O₂as an oxidant

Takeshi Yatabe, Takahiro Kikunaga, Takahiro Matsumoto, Hidetaka Nakai, Ki Seok Yoon, Seiji Ogo

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2 Citations (Scopus)

Abstract

We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

Original language	English
Pages (from-to)	1380-1382
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	8
DOIs	https://doi.org/10.1246/cl.140376
Publication status	Published - 2014

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.140376

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title = "Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant",

abstract = "We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.",

author = "Takeshi Yatabe and Takahiro Kikunaga and Takahiro Matsumoto and Hidetaka Nakai and Yoon, {Ki Seok} and Seiji Ogo",

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journal = "Chemistry Letters",

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T1 - Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

AU - Yatabe, Takeshi

AU - Kikunaga, Takahiro

AU - Matsumoto, Takahiro

AU - Nakai, Hidetaka

AU - Yoon, Ki Seok

AU - Ogo, Seiji

PY - 2014

Y1 - 2014

N2 - We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

AB - We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

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U2 - 10.1246/cl.140376

DO - 10.1246/cl.140376

M3 - Article

AN - SCOPUS:84906505063

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

Synthesis of aqueous-stable and water-soluble mononuclear nonheme Mn^V-Oxo complexes using H₂O₂as an oxidant

Abstract

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