Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe, Takahiro Kikunaga, Takahiro Matsumoto, Hidetaka Nakai, Ki Suk Yoon, Seiji Ogo

Research output: Contribution to journalArticle

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Abstract

We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

Original languageEnglish
Pages (from-to)1380-1382
Number of pages3
JournalChemistry Letters
Volume43
Issue number8
DOIs
Publication statusPublished - Jan 1 2014

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Manganese
Oxidants
Water
Hydrogen Peroxide
Crystal structure
Derivatives

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant. / Yatabe, Takeshi; Kikunaga, Takahiro; Matsumoto, Takahiro; Nakai, Hidetaka; Yoon, Ki Suk; Ogo, Seiji.

In: Chemistry Letters, Vol. 43, No. 8, 01.01.2014, p. 1380-1382.

Research output: Contribution to journalArticle

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AU - Yoon, Ki Suk

AU - Ogo, Seiji

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