Synthesis of A2B2 type cis-doubly N-confused porphyrins from N-confused dipyrromethanes

Hiromitsu Maeda, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A2B2 type of cis-doubly N-confused porphyrins (cis-N2CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated.

Original languageEnglish
Pages (from-to)2427-2432
Number of pages6
JournalTetrahedron
Volume60
Issue number10
DOIs
Publication statusPublished - Mar 1 2004

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Bearings (structural)
Porphyrins
Complexation
Condensation
Metals
Oxidation
dipyrromethane
pentafluorobenzaldehyde

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Synthesis of A2B2 type cis-doubly N-confused porphyrins from N-confused dipyrromethanes. / Maeda, Hiromitsu; Osuka, Atsuhiro; Furuta, Hiroyuki.

In: Tetrahedron, Vol. 60, No. 10, 01.03.2004, p. 2427-2432.

Research output: Contribution to journalArticle

Maeda, Hiromitsu ; Osuka, Atsuhiro ; Furuta, Hiroyuki. / Synthesis of A2B2 type cis-doubly N-confused porphyrins from N-confused dipyrromethanes. In: Tetrahedron. 2004 ; Vol. 60, No. 10. pp. 2427-2432.
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