Synthesis of A2B2 type cis-doubly N-confused porphyrins from N-confused dipyrromethanes

Hiromitsu Maeda; Atsuhiro Osuka; Hiroyuki Furuta

doi:10.1016/j.tet.2003.12.051

Synthesis of A₂B₂ type cis-doubly N-confused porphyrins from N-confused dipyrromethanes

Hiromitsu Maeda, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A₂B₂ type of cis-doubly N-confused porphyrins (cis-N₂CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated.

Original language	English
Pages (from-to)	2427-2432
Number of pages	6
Journal	Tetrahedron
Volume	60
Issue number	10
DOIs	https://doi.org/10.1016/j.tet.2003.12.051
Publication status	Published - Mar 1 2004

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2003.12.051

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abstract = "A2B2 type of cis-doubly N-confused porphyrins (cis-N2CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated.",

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AU - Maeda, Hiromitsu

AU - Osuka, Atsuhiro

AU - Furuta, Hiroyuki

PY - 2004/3/1

Y1 - 2004/3/1

N2 - A2B2 type of cis-doubly N-confused porphyrins (cis-N2CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated.

AB - A2B2 type of cis-doubly N-confused porphyrins (cis-N2CP) bearing 2,6-dichloro-, 2-nitro-, 3-nitro-, and 4-nitro-phenyl groups and pentafluorophenyl groups at meso-positions were synthesized by the condensation of aryl-substituted N-confused dipyrromethanes and pentafluorobenzaldehyde. The complexation of rare high oxidation states of metals, Cu(III) and Ag(III), was demonstrated.

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Synthesis of A₂B₂ type cis-doubly N-confused porphyrins from N-confused dipyrromethanes

Abstract

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