@article{339643462dd5416ea5e5fa170bfe88e5,
title = " Synthesis of CH 2 -Linked α(1,6)-Disaccharide Analogues by α-Selective Radical Coupling C-Glycosylation ",
abstract = " C-Linked carbohydrate structure, in which the cleavable O-glycosidic linkage is replaced by a carbon unit, is a useful tool for functional analyses of glycoconjugates. We describe a synthetic method for α-CH 2 -linked disaccharide structures, such as Glc(1,6)-Glc, by stereoselective radical-coupling C-glycosylation between a conformationally constrained and stable C1-sp 3 hybridized xanthate donor and a carefully designed acceptor. ",
author = "Noriaki Kiya and Yu Hidaka and Kazuteru Usui and Go Hirai",
note = "Funding Information: This study was partially supported by PRIME (Grant Number JP18gm5910018) and Platform Project for Supporting Drug Discovery and Life Science Research (BINDS, Grant Number JP18am0101091) from the Japan Agency for Medical Research and Development, AMED, and the JSPS KAKENHI (Grant Numbers 16H01167 and 18H04417 for Middle Molecular Strategy and 18H02097) and JSPS A3 Foresight Program. We also thank Mr. Arunpuksakul Nontapat (Chulalongkorn University, Thailand) for his technical support. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",
year = "2019",
month = mar,
day = "15",
doi = "10.1021/acs.orglett.9b00133",
language = "English",
volume = "21",
pages = "1588--1592",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "6",
}