Synthesis of Cp-Re complexes via olefinic C-H activation and successive formation of cyclopentadienes

Yoichiro Kuninobu, Yuta Nishina, Takashi Matsuki, Kazuhiko Takai

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Treatment of an α,β-unsaturated ketimine with an α,β-unsaturated carbonyl compound in the presence of a rhenium complex, Re2(CO)10, gave a cyclopentadienyl-rhenium complex. This reaction proceeds via rhenium-catalyzed C-H bond activation of an olefinic C-H bond, insertion of an α,β-unsaturated carbonyl compound into a Re-C bond of the alkenylrhenium intermediate, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline to give a cyclopentadiene derivative, followed by the formation of a cyclopentadienyl-rhenium complex from the cyclopentadiene derivative and the rhenium complex.

Original languageEnglish
Pages (from-to)14062-14063
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number43
DOIs
Publication statusPublished - Oct 29 2008
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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