Synthesis of FeOF using roll-quenching method and the cathode properties for lithium-ion battery

Ayuko Kitajou, Hideyuki Komatsu, Rintarou Nagano, Shigeto Okada

Research output: Contribution to journalArticle

Abstract

Rutile-type FeOF is a promising cathode for lithium-ion batteries, because it has a relatively large theoretical capacity of 885 mAh g-1 in eco-friendly iron-based cathodes. Although it is difficult to synthesize by conventional solid-state synthesis methods, it can be quickly synthesized by the roll-quenching method. The quick synthesis method is suitable to reduce the produce cost, but also to avoid the fluorine gas release during synthesis procedure. The obtained FeOF by roll-quenching method has kept some crystallinities, and provides a large discharge capacity (900 mAh g-1) between 0.7 and 4.0 V. The charge and discharge reaction mechanism was investigated by structural analyses.

Original languageEnglish
Pages (from-to)494-498
Number of pages5
JournalJournal of Power Sources
Volume243
DOIs
Publication statusPublished - 2013

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this