Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states

Alagar Srinivasan, Motoki Toganoh, Teppei Niino, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.

Original languageEnglish
Pages (from-to)11305-11313
Number of pages9
JournalInorganic chemistry
Volume47
Issue number23
DOIs
Publication statusPublished - Dec 1 2008

Fingerprint

Rhodium
rhodium
Metals
Oxidation
oxidation
Porphyrins
synthesis
porphyrins
metals
Physical properties
physical properties
Ligands
ligands
tetraphenylporphyrin

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states. / Srinivasan, Alagar; Toganoh, Motoki; Niino, Teppei; Osuka, Atsuhiro; Furuta, Hiroyuki.

In: Inorganic chemistry, Vol. 47, No. 23, 01.12.2008, p. 11305-11313.

Research output: Contribution to journalArticle

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