Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states

Alagar Srinivasan, Motoki Toganoh, Teppei Niino, Atsuhiro Osuka, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    34 Citations (Scopus)

    Abstract

    A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.

    Original languageEnglish
    Pages (from-to)11305-11313
    Number of pages9
    JournalInorganic chemistry
    Volume47
    Issue number23
    DOIs
    Publication statusPublished - Dec 1 2008

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

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