Synthesis of N-methylmorpholine N-(17O-oxide) and N-methylmorpholine 15N-(17O-oxide)

Martina Opietnik, Antje Potthast, Takuya Kitaoka, Thomas Rosenau

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

N-Methylmorpholine N-(17O-oxide) and N-methylmorpholine 15N-(17O-oxide) were prepared from N-methylmorpholine and 15N-methylmorpholine by oxidation with H2 17O2. The facile one-pot procedure provided yields of 82 and 76%, respectively. The labeled hydrogen peroxide was obtained by electrolysis of H2 17O followed by autoxidation of 2-ethylanthraquinol with the molecular oxygen 17O2 generated. The compounds serve for mechanistic studies into gold nanoparticle generation in NMMO solution.

Original languageEnglish
Pages (from-to)78-80
Number of pages3
JournalJournal of Labelled Compounds and Radiopharmaceuticals
Volume53
Issue number2
DOIs
Publication statusPublished - Feb 1 2010

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Biochemistry
  • Radiology Nuclear Medicine and imaging
  • Drug Discovery
  • Spectroscopy
  • Organic Chemistry

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