TY - JOUR
T1 - Synthesis of organosulfides using transition-metal-catalyzed substitution reactions
T2 - To construct exergonic reactions employing metal inorganic and organic co-substrate/co-product methods
AU - Arisawa, Mieko
N1 - Funding Information:
This work was supported by a Grant-in-Aid for the Scientific Research (Nos. 22689001 and 25109503 ) and Asahi Glass Foundation .
PY - 2014/6/4
Y1 - 2014/6/4
N2 - A catalyst changes the course of a reaction without affecting the relative thermodynamic stability of substrates and products, and a catalytic reaction must be exergonic in order to obtain high yields of the product and to attain reasonable reaction rates. In the case that the desired reaction is in equilibrium or is endergonic, devices for making products thermodynamically more stable than substrates are needed. In this review, the transition-metal- catalyzed synthesis of organosulfides using a substitution reaction is summarized, where metal inorganic and organic co-substrate/co-product methods are used in developing exergonic reactions.
AB - A catalyst changes the course of a reaction without affecting the relative thermodynamic stability of substrates and products, and a catalytic reaction must be exergonic in order to obtain high yields of the product and to attain reasonable reaction rates. In the case that the desired reaction is in equilibrium or is endergonic, devices for making products thermodynamically more stable than substrates are needed. In this review, the transition-metal- catalyzed synthesis of organosulfides using a substitution reaction is summarized, where metal inorganic and organic co-substrate/co-product methods are used in developing exergonic reactions.
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U2 - 10.1016/j.tetlet.2014.04.081
DO - 10.1016/j.tetlet.2014.04.081
M3 - Review article
AN - SCOPUS:84901483351
VL - 55
SP - 3391
EP - 3399
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 23
ER -