TY - JOUR
T1 - Synthesis of pyridine N-oxide-BF2CF3 complexes and their fluorescence properties
AU - Nishida, Tomoaki
AU - Fukazawa, Aiko
AU - Yamaguchi, Eriko
AU - Oshima, Hiroya
AU - Yamaguchi, Shigehiro
AU - Kanai, Motomu
AU - Kuninobu, Yoichiro
N1 - Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 2014/4
Y1 - 2014/4
N2 - Pyridine N-oxide-BF2CF3 and-BF2C 2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials. Too complex for simple answers: Complexes of pyridine N-oxide with BF2CF3 and BF 2C2F5, and their derivatives were synthesized. Most of the complexes fluoresce, both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. Owing to their properties such complexes hold potential as organic functional materials.
AB - Pyridine N-oxide-BF2CF3 and-BF2C 2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials. Too complex for simple answers: Complexes of pyridine N-oxide with BF2CF3 and BF 2C2F5, and their derivatives were synthesized. Most of the complexes fluoresce, both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. Owing to their properties such complexes hold potential as organic functional materials.
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U2 - 10.1002/asia.201301688
DO - 10.1002/asia.201301688
M3 - Article
C2 - 24519930
AN - SCOPUS:84897107992
SN - 1861-4728
VL - 9
SP - 1026
EP - 1030
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 4
ER -