Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

Yoshifumi Amamoto, Yuji Higaki, Hideyuki Otsuka, Atsushi Takahara

Research output: Contribution to conferencePaper

Abstract

Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

Original languageEnglish
Number of pages1
Publication statusPublished - Oct 18 2006
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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    Amamoto, Y., Higaki, Y., Otsuka, H., & Takahara, A. (2006). Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. Paper presented at 55th SPSJ Annual Meeting, Nagoya, Japan.