Synthesis of Stereoselectively Functionalized Silacyclopentanes

Kazunobu Igawa; Akihiro Kuroo; Daisuke Yoshihiro; Yuki Yamanaka; Katsuhiko Tomooka

doi:10.1055/s-0036-1590826

Synthesis of Stereoselectively Functionalized Silacyclopentanes

Kazunobu Igawa, Akihiro Kuroo, Daisuke Yoshihiro, Yuki Yamanaka, Katsuhiko Tomooka

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

Original language	English
Pages (from-to)	2445-2448
Number of pages	4
Journal	Synlett
Volume	28
Issue number	18
DOIs	https://doi.org/10.1055/s-0036-1590826
Publication status	Published - Nov 13 2017

All Science Journal Classification (ASJC) codes

Organic Chemistry

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abstract = "An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.",

author = "Kazunobu Igawa and Akihiro Kuroo and Daisuke Yoshihiro and Yuki Yamanaka and Katsuhiko Tomooka",

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AU - Igawa, Kazunobu

AU - Kuroo, Akihiro

AU - Yoshihiro, Daisuke

AU - Yamanaka, Yuki

AU - Tomooka, Katsuhiko

N1 - Funding Information: This research was supported by JSPS KAKENHI Grants JP16K13955, JP15K13697, and 17H06235, Integrated Research Consortium on Chemical Sciences, the Cooperative Research Program of ‘Network

PY - 2017/11/13

Y1 - 2017/11/13

N2 - An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

AB - An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

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Synthesis of Stereoselectively Functionalized Silacyclopentanes

Abstract

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