Synthesis of Stereoselectively Functionalized Silacyclopentanes

Kazunobu Igawa, Akihiro Kuroo, Daisuke Yoshihiro, Yuki Yamanaka, Katsuhiko Tomooka

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by Mitsunobu reaction or Tsuji-Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.

Original languageEnglish
Pages (from-to)2445-2448
Number of pages4
JournalSynlett
Volume28
Issue number18
DOIs
Publication statusPublished - Nov 13 2017

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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