Synthesis of unsymmetrical polyfluorinated diaryl sulfides by rhodium-catalyzed aryl exchange reaction

Mieko Arisawa, Takuya Ichikawa, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

RhH(PPh3)4 and 1,2-bis(diphenylphosphino)benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the reaction of symmetrical polyfluorinated diaryl sulfides and substituted pentafluorobenzenes in the presence of triisopropylsilane.

Original languageEnglish
Pages (from-to)4327-4329
Number of pages3
JournalTetrahedron Letters
Volume54
Issue number32
DOIs
Publication statusPublished - Aug 7 2013
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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