Synthesis of well-defined poly(styrene)-b-poly(p-tert-butoxystyrene) multiblock copolymer from poly(alkoxyamine) macroinitiator

Yuji Higaki, Hideyuki Otsuka, Atsushi Takahara

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The stepwise insertion reaction of styrene (St) and p-tert-butoxystyrene (BOSt) into poly(alkoxyamine) macroinitiator was carried out to provide well-defined poly(St)-b-poly(BOSt) multiblock copolymers. Structural confirmation of the multiblock copolymers was accomplished by NMR and IR measurements. The model reaction also supported that the monomer insertion into the macroinitiator proceeded in accordance with a living fashion.

Original languageEnglish
Pages (from-to)7095-7101
Number of pages7
Journalpolymer
Volume44
Issue number23
DOIs
Publication statusPublished - Oct 17 2003

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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