Synthesis, physical properties, and structure of TIPS-difuranoacenes

Motonori Watanabe, Ching Ting Chien, Yan Duo Lin, Yuan Jay Chang, Yuh Sheng Wen, Kenta Goto, Masahiko Shibahara, Teruo Shinmyozu, Tahsin J. Chow

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The synthesis, physical properties, and structure of triisopropylsilylethynyltetracenodifuran (2) and pentacenodifuran (3) derivatives were reported. There showed high stability in solution in the dark, yet decomposed under light. Single crystal of pentacenodifuran was analyzed by X-ray diffraction analysis, and showed one dimensional packing array along the c-axis. The molecules were stacked with a 3.30 Å interlayer distance. The crystals exhibited a high thermal stability under an ambient condition.

Original languageEnglish
Pages (from-to)1424-1427
Number of pages4
JournalTetrahedron Letters
Volume55
Issue number8
DOIs
Publication statusPublished - Feb 19 2014

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X-Ray Diffraction
X ray diffraction analysis
Thermodynamic stability
Physical properties
Hot Temperature
Single crystals
Derivatives
Light
Crystals
Molecules

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Synthesis, physical properties, and structure of TIPS-difuranoacenes. / Watanabe, Motonori; Chien, Ching Ting; Lin, Yan Duo; Chang, Yuan Jay; Wen, Yuh Sheng; Goto, Kenta; Shibahara, Masahiko; Shinmyozu, Teruo; Chow, Tahsin J.

In: Tetrahedron Letters, Vol. 55, No. 8, 19.02.2014, p. 1424-1427.

Research output: Contribution to journalArticle

Watanabe, M, Chien, CT, Lin, YD, Chang, YJ, Wen, YS, Goto, K, Shibahara, M, Shinmyozu, T & Chow, TJ 2014, 'Synthesis, physical properties, and structure of TIPS-difuranoacenes', Tetrahedron Letters, vol. 55, no. 8, pp. 1424-1427. https://doi.org/10.1016/j.tetlet.2014.01.036
Watanabe, Motonori ; Chien, Ching Ting ; Lin, Yan Duo ; Chang, Yuan Jay ; Wen, Yuh Sheng ; Goto, Kenta ; Shibahara, Masahiko ; Shinmyozu, Teruo ; Chow, Tahsin J. / Synthesis, physical properties, and structure of TIPS-difuranoacenes. In: Tetrahedron Letters. 2014 ; Vol. 55, No. 8. pp. 1424-1427.
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