Synthesis, physical properties, and structure of TIPS-difuranoacenes

Motonori Watanabe, Ching Ting Chien, Yan Duo Lin, Yuan Jay Chang, Yuh Sheng Wen, Kenta Goto, Masahiko Shibahara, Teruo Shinmyozu, Tahsin J. Chow

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The synthesis, physical properties, and structure of triisopropylsilylethynyltetracenodifuran (2) and pentacenodifuran (3) derivatives were reported. There showed high stability in solution in the dark, yet decomposed under light. Single crystal of pentacenodifuran was analyzed by X-ray diffraction analysis, and showed one dimensional packing array along the c-axis. The molecules were stacked with a 3.30 Å interlayer distance. The crystals exhibited a high thermal stability under an ambient condition.

Original languageEnglish
Pages (from-to)1424-1427
Number of pages4
JournalTetrahedron Letters
Volume55
Issue number8
DOIs
Publication statusPublished - Feb 19 2014

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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