Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex

Takehiro Ohta, Takashi Tachiyama, Kazunari Yoshizawa, Tokio Yamabe

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A disulfide-bridged dicopper(I) complex [Cu2(Py2SSPy2)](ClO4)2 (1), synthesized by the redox reaction of a Cu(II) salt with a thiol-containing N3S-donor ligand, N,N-bis[2-(2-pyridyl)ethyl]-2-mercapto-2-methylpropylamine (Py2SH), is demonstrated to catalyze epoxidation and hydroxylation with H2O2 as an oxidant. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)2581-2585
Number of pages5
JournalTetrahedron Letters
Volume41
Issue number15
DOIs
Publication statusPublished - Apr 8 2000
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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