Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex

Takehiro Ohta, Takashi Tachiyama, Kazunari Yoshizawa, Tokio Yamabe

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A disulfide-bridged dicopper(I) complex [Cu2(Py2SSPy2)](ClO4)2 (1), synthesized by the redox reaction of a Cu(II) salt with a thiol-containing N3S-donor ligand, N,N-bis[2-(2-pyridyl)ethyl]-2-mercapto-2-methylpropylamine (Py2SH), is demonstrated to catalyze epoxidation and hydroxylation with H2O2 as an oxidant. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)2581-2585
Number of pages5
JournalTetrahedron Letters
Volume41
Issue number15
DOIs
Publication statusPublished - Apr 8 2000
Externally publishedYes

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Hydroxylation
Epoxidation
Redox reactions
Sulfhydryl Compounds
Oxidants
Disulfides
Oxidation-Reduction
Salts
Ligands
perchlorate

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex. / Ohta, Takehiro; Tachiyama, Takashi; Yoshizawa, Kazunari; Yamabe, Tokio.

In: Tetrahedron Letters, Vol. 41, No. 15, 08.04.2000, p. 2581-2585.

Research output: Contribution to journalArticle

Ohta, Takehiro ; Tachiyama, Takashi ; Yoshizawa, Kazunari ; Yamabe, Tokio. / Synthesis, structure, and catalytic function of a disulfide-bridged dicopper(I) complex. In: Tetrahedron Letters. 2000 ; Vol. 41, No. 15. pp. 2581-2585.
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