Synthesis, structure, and dissociation equilibrium of [Co(η5-C5H5) (Se2C6H4)]2, a novel metalladiselenolene complex

Satoru Habe, Teppei Yamada, Takuya Nankawa, Jun Mizutani, Masaki Murata, Hiroshi Nishihara

Research output: Contribution to journalArticle

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Abstract

A (phenylenediselenolato)cobalt complex dimer, [Co(η5-C5H5) (Se2C6H4)]2 (1), was synthesized by a reaction of carbonyl(η5-cyclopentadienyl)diiodocobalt(III) ([Co(η5-C5H5)I2(CO)]) with poly(o-diselenobenzene). The structure of 1, determined by single-crystal X-ray crystallography, was found to be located in the space group of P21/c (No. 14), with a = 9.3346(5) Å, b = 11.6477(9) Å, c = 10.2179(5) Å, β = 111.491(1)°, and Z = 2. Covalent Co-Se bonds bridge the metal centers. In solution, dimers and monomers coexist at equilibrium. The dissociation equilibrium constant of 1 in solution was evaluated by 1H NMR spectra at several temperatures between 20 and 80 °C. Dissociation enthalpies/entropies were found to be 50/110, 60/120, and 88 kJ mol-1/200 J K-1 mol-1 in dimethyl sulfoxide-d6, benzene-d6, and chloroform-d1, respectively.

Original languageEnglish
Pages (from-to)1952-1955
Number of pages4
JournalInorganic Chemistry
Volume42
Issue number6
DOIs
Publication statusPublished - Mar 24 2003
Externally publishedYes

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Dimers
dimers
dissociation
X ray crystallography
Equilibrium constants
Carbon Monoxide
synthesis
Chloroform
Dimethyl Sulfoxide
Cobalt
Benzene
chloroform
crystallography
Enthalpy
Entropy
cobalt
monomers
Monomers
enthalpy
Metals

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Synthesis, structure, and dissociation equilibrium of [Co(η5-C5H5) (Se2C6H4)]2, a novel metalladiselenolene complex. / Habe, Satoru; Yamada, Teppei; Nankawa, Takuya; Mizutani, Jun; Murata, Masaki; Nishihara, Hiroshi.

In: Inorganic Chemistry, Vol. 42, No. 6, 24.03.2003, p. 1952-1955.

Research output: Contribution to journalArticle

Habe, Satoru ; Yamada, Teppei ; Nankawa, Takuya ; Mizutani, Jun ; Murata, Masaki ; Nishihara, Hiroshi. / Synthesis, structure, and dissociation equilibrium of [Co(η5-C5H5) (Se2C6H4)]2, a novel metalladiselenolene complex. In: Inorganic Chemistry. 2003 ; Vol. 42, No. 6. pp. 1952-1955.
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