Synthesis, structure and magnetic properties of a cyano-bridged dinuclear compound fac-{[FeIII(pzTp)(CN)2(μ-CN)] Cu II(TPyA)}·Et2O·ClO4 (pzTp = tetrakis(pyrazolyl)borate)

Da Yu Wu, Osamu Sato

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The reaction of tricyanometallate precursor, (Bu4N)[(pzTp)Fe(CN) 3] with Cu(ClO4)2·6H2O in the presence of the tetradentate ligand tris(2-pyridylmethyl)amine (TPyA) afford the dinuclear compound fac-{[FeIII(pzTp)(CN)2(μ-CN)] CuII(TPA)} ·Et2O·ClO4 (1) (pzTp = tetrakis(pyrazolyl)borate). The molecular structure was determined by single-crystal X-ray diffraction. In compound 1, the FeIII ion is coordinated by three cyanide carbon atoms and three nitrogen atoms of pzTp anions. Whereas, the CuII ion is surrounded by one cyanide nitrogen atom and four nitrogen atoms from the TPyA ligand. Magnetic measurements indicate the intramolecular ferromagnetic coupling is observed for compound 1, and it has S = 1 ground states.

Original languageEnglish
Pages (from-to)389-392
Number of pages4
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume635
Issue number2
DOIs
Publication statusPublished - Feb 1 2009

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Synthesis, structure and magnetic properties of a cyano-bridged dinuclear compound fac-{[Fe<sup>III</sup>(pzTp)(CN)<sub>2</sub>(μ-CN)] Cu <sup>II</sup>(TPyA)}·Et<sub>2</sub>O·ClO<sub>4</sub> (pzTp = tetrakis(pyrazolyl)borate)'. Together they form a unique fingerprint.

  • Cite this