Synthesis, structure and magnetic properties of a linear Cu(II)Cu(II)Gd(III) complex

Masaaki Ohba, Nobuto Ohtsubo, Takuya Shiga, Masatomi Sakamoto, Hisashi Okawa

Research output: Contribution to journalArticle

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Abstract

A dimetallic trinuclear Cu(II)2Gd(III) complex, [Cu2(L)][Gd(hfac)3] (1: H4L = 3,3′- (1,2-ethanediyldinitrilo)bis(1-o-hydroxyphenyl-1-butaneonato), hfac- = hexafluoroacetylacetonate ion) has been synthesized, and structurally and magnetically characterized. [Cu2(L)] unit coordinates to [Gd(hfac)3] through two phenolate oxygen atoms to afford a linear Cu(II)-Cu(II)-Gd(III) system. Its magnetic property is dominated by the antiferromagnetic interaction between two Cu2+ ions, and the Gd3+ ion behaves like a magnetically isolated ion.

Original languageEnglish
Pages (from-to)1905-1910
Number of pages6
JournalPolyhedron
Volume22
Issue number14-17
DOIs
Publication statusPublished - Jul 15 2003

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Magnetic properties
Ions
magnetic properties
synthesis
ions
oxygen atoms
Oxygen
Atoms
interactions

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis, structure and magnetic properties of a linear Cu(II)Cu(II)Gd(III) complex. / Ohba, Masaaki; Ohtsubo, Nobuto; Shiga, Takuya; Sakamoto, Masatomi; Okawa, Hisashi.

In: Polyhedron, Vol. 22, No. 14-17, 15.07.2003, p. 1905-1910.

Research output: Contribution to journalArticle

Ohba, Masaaki ; Ohtsubo, Nobuto ; Shiga, Takuya ; Sakamoto, Masatomi ; Okawa, Hisashi. / Synthesis, structure and magnetic properties of a linear Cu(II)Cu(II)Gd(III) complex. In: Polyhedron. 2003 ; Vol. 22, No. 14-17. pp. 1905-1910.
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AU - Okawa, Hisashi

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