Abstract
We synthesized new Fe(II) compounds consisting of [Fe(L)2] (HL: 2-Acetylpyridine isonicotinoylhydrazone) and dicarboxylic acids. Single crystal analysis shows that short hydrogen bonds are formed between [Fe(L)2] and dicarboxylic acids. The hydrogen bonding interactions between metal complexes and dicarboxylic acids are complemented by π-π interactions, forming two-dimensional network structures. Magnetic properties show that the Fe(II) compounds exhibit gradual spin crossover behavior around room temperature and a T1/2 value is dependent on the halogen substituent on the dicarboxylic acids.
Original language | English |
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Article number | 131 |
Journal | Crystals |
Volume | 6 |
Issue number | 10 |
DOIs | |
Publication status | Published - Jan 1 2016 |
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Materials Science(all)
- Condensed Matter Physics
- Inorganic Chemistry