Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 x 3] square grid generated by a strict self-assembly process

Liang Zhao, Zhiqiang Xu, Laurence K. Thompson, Sarah L. Heath, David O. Miller, Masaaki Ohba

Research output: Contribution to journalArticlepeer-review

93 Citations (Scopus)

Abstract

A ligand with a linear arrangement of three coordination pockets produces a Cu9O12, alkoxide-bridged, square grid of closely spaced copper centers (see picture) in high yield by a strict self-assembly process. Orthogonal bridging connections within the grid lead to dominant intramolecular ferromagnetic coupling with a high-spin ground state.

Original languageEnglish
Pages (from-to)3114-3117
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number17
DOIs
Publication statusPublished - Sep 1 2000

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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