Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexane-diamine; MIII = Fe, Co)

Nobuo Fukita, Masaaki Ohba, Hisashi Okawa

Research output: Contribution to journalConference article

6 Citations (Scopus)

Abstract

A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.

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Diamines
Cyanides
Magnetism
cyanides
Cyclohexane
diamines
cyclohexane
assemblies
spin exchange
X ray crystallography
Exchange interactions
synthesis
linkages
crystallography
Magnetization
Ions
ions
x rays
interactions

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

Cite this

@article{2c4adbad08b741f0a45900569114d88d,
title = "Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexane-diamine; MIII = Fe, Co)",
abstract = "A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.",
author = "Nobuo Fukita and Masaaki Ohba and Hisashi Okawa",
year = "2000",
month = "1",
day = "1",
doi = "10.1080/10587250008038268",
language = "English",
volume = "342",
pages = "217--224",
journal = "Molecular Crystals and Liquid Crystals",
issn = "1542-1406",
publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexane-diamine; MIII = Fe, Co)

AU - Fukita, Nobuo

AU - Ohba, Masaaki

AU - Okawa, Hisashi

PY - 2000/1/1

Y1 - 2000/1/1

N2 - A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.

AB - A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.

UR - http://www.scopus.com/inward/record.url?scp=0033652121&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033652121&partnerID=8YFLogxK

U2 - 10.1080/10587250008038268

DO - 10.1080/10587250008038268

M3 - Conference article

AN - SCOPUS:0033652121

VL - 342

SP - 217

EP - 224

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

SN - 1542-1406

ER -