A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.
|Number of pages||8|
|Journal||Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals|
|Publication status||Published - 2000|
|Event||Proceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) - Kyoto, Jpn|
Duration: Nov 30 1999 → Dec 2 1999
All Science Journal Classification (ASJC) codes
- Condensed Matter Physics