Synthesis, structure and properties of novel homochiral metal-organic coordination polymers

Wan Chen, Sheng Qun Su, Shu Yan Song, Xue Zhi Song, Hong Jie Zhang

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Two new homochiral metal-organic coordination polymers[M(D-cam)(H 2mbdpz)] n[M=Zn(complex 1), Co(complex 2); D-H 2cam=D-(+)-camphoric acid, H 2mbdpz=4, 4'-methylenebis(3, 5-dime-{thylpyrazole})] were prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions. The complexes were characterized by means of single-crystal X-ray diffraction, elemental analysis, thermograrimetri analysis(TGA), powder X-ray diffraction(XRD) and photoluminescent(PL) spectrometry. X-ray crystallography reveals that complexes 1 and 2 are isomorphous and homochiral, exhibiting the three-dimensional open structure with a ThSi 2 type of uninodal 3-connected networks.

Original languageEnglish
Pages (from-to)215-218
Number of pages4
JournalGaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume33
Issue number2
DOIs
Publication statusPublished - Feb 2012
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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