Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

Atsushi Ikegami, Masaaki Abe, Atsushi Inatomi, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    8 Citations (Scopus)

    Abstract

    At the right places: Owing to substitution-lability difference in disparate metal centers, an oxo-centered heterometallic trinuclear acetato complex [Ru2MgO(CH3COO)6(Py)3] (py=pyridine; see picture) undergoes site-selective substitution of propionates and ferrocenycarboxylates in a stepwise manner. The new substituted families have been successfully separated by chromatography and fully characterized. (Chemical Figure Presented)

    Original languageEnglish
    Pages (from-to)4438-4441
    Number of pages4
    JournalChemistry - A European Journal
    Volume16
    Issue number15
    DOIs
    Publication statusPublished - Apr 19 2010

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Organic Chemistry

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