Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

Atsushi Ikegami, Masaaki Abe, Atsushi Inatomi, Yoshio Hisaeda

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8 Citations (Scopus)

Abstract

At the right places: Owing to substitution-lability difference in disparate metal centers, an oxo-centered heterometallic trinuclear acetato complex [Ru2MgO(CH3COO)6(Py)3] (py=pyridine; see picture) undergoes site-selective substitution of propionates and ferrocenycarboxylates in a stepwise manner. The new substituted families have been successfully separated by chromatography and fully characterized. (Chemical Figure Presented)

Original languageEnglish
Pages (from-to)4438-4441
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number15
DOIs
Publication statusPublished - Apr 19 2010

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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