Tailoring widely used ammonia synthesis catalysts for H and N poisoning resistance

Kulbir Kaur Ghuman, Kota Tozaki, Masaaki Sadakiyo, Sho Kitano, Takashi Oyabe, Miho Yamauchi

Research output: Contribution to journalArticle

Abstract

Despite many advancements, an inexpensive ammonia synthesis catalyst free from hydrogen and nitrogen poisoning, and capable of synthesizing ammonia under mild conditions is still unknown and is long sought-after. Here we present an active nanoalloy catalyst, RuFe, formed by alloying highly active Ru and inexpensive Fe, capable of activating both N 2 and H 2 without blocking the surface active sites and thereby overcoming the major hurdle faced by the current best performing pure metal catalysts. This novel RuFe nanoalloy catalyst operates under milder conditions than the conventional Fe catalyst and is less expensive than the so far best performing Ru-based catalysts providing additional advantages. Most importantly, by integrating theory and experiments, we identified the underlying mechanisms responsible for lower surface poisoning of this catalyst, which will provide directions for fabricating poison-free efficient NH 3 synthesis catalysts in future.

Original languageEnglish
Pages (from-to)5117-5122
Number of pages6
JournalPhysical Chemistry Chemical Physics
Volume21
Issue number9
DOIs
Publication statusPublished - Jan 1 2019

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Catalyst poisoning
poisoning
Ammonia
ammonia
catalysts
Catalysts
synthesis
poisons
Poisons
Alloying
alloying
Hydrogen
Nitrogen
Metals
nitrogen

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Tailoring widely used ammonia synthesis catalysts for H and N poisoning resistance. / Ghuman, Kulbir Kaur; Tozaki, Kota; Sadakiyo, Masaaki; Kitano, Sho; Oyabe, Takashi; Yamauchi, Miho.

In: Physical Chemistry Chemical Physics, Vol. 21, No. 9, 01.01.2019, p. 5117-5122.

Research output: Contribution to journalArticle

Ghuman, Kulbir Kaur ; Tozaki, Kota ; Sadakiyo, Masaaki ; Kitano, Sho ; Oyabe, Takashi ; Yamauchi, Miho. / Tailoring widely used ammonia synthesis catalysts for H and N poisoning resistance. In: Physical Chemistry Chemical Physics. 2019 ; Vol. 21, No. 9. pp. 5117-5122.
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