Temperature dependence of block copolymer thin films with different film thickness

Naoya Torikai; Daisuke Kawaguchi; Atsushi Takano; Yushu Matsushita; Robert Dalgliesh; Sean Langridge

Temperature dependence of block copolymer thin films with different film thickness

Naoya Torikai, Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita, Robert Dalgliesh, Sean Langridge

Research output: Contribution to conference › Paper › peer-review

Abstract

Interfacial structure of a styrene-d8-2-vinylpyridine diblock copolymer thin films with lamellar microdomain was investigated by neutron reflectivity (NR) measurement at different temperatures above Tg of the component polymer. The thin film specimens with different film thicknesses were prepared by spin-coating method, and then annealed at 170°C in vacuum during more than one week before NR measurement. The observed specular reflectivity profiles exhibit several Bragg peaks up to high order, implying that the lamellar structure keeps highly-ordered state and preferential orientation along the direction parallel to the film surface even at high temperature above Tg. Further, it was found that the temperature dependence of lamellar domain spacing is different according the difference in total film thickness.

Original language	English
Pages	3281-3282
Number of pages	2
Publication status	Published - Dec 1 2005
Externally published	Yes
Event	54th SPSJ Symposium on Macromolecules - Yamagata, Japan Duration: Sept 20 2005 → Sept 22 2005

Other

Other	54th SPSJ Symposium on Macromolecules
Country/Territory	Japan
City	Yamagata
Period	9/20/05 → 9/22/05

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

@conference{ef901797430d42019e3e585d4283e87b,

title = "Temperature dependence of block copolymer thin films with different film thickness",

abstract = "Interfacial structure of a styrene-d8-2-vinylpyridine diblock copolymer thin films with lamellar microdomain was investigated by neutron reflectivity (NR) measurement at different temperatures above Tg of the component polymer. The thin film specimens with different film thicknesses were prepared by spin-coating method, and then annealed at 170°C in vacuum during more than one week before NR measurement. The observed specular reflectivity profiles exhibit several Bragg peaks up to high order, implying that the lamellar structure keeps highly-ordered state and preferential orientation along the direction parallel to the film surface even at high temperature above Tg. Further, it was found that the temperature dependence of lamellar domain spacing is different according the difference in total film thickness.",

author = "Naoya Torikai and Daisuke Kawaguchi and Atsushi Takano and Yushu Matsushita and Robert Dalgliesh and Sean Langridge",

year = "2005",

month = dec,

day = "1",

language = "English",

pages = "3281--3282",

note = "54th SPSJ Symposium on Macromolecules ; Conference date: 20-09-2005 Through 22-09-2005",

}

TY - CONF

T1 - Temperature dependence of block copolymer thin films with different film thickness

AU - Torikai, Naoya

AU - Kawaguchi, Daisuke

AU - Takano, Atsushi

AU - Matsushita, Yushu

AU - Dalgliesh, Robert

AU - Langridge, Sean

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Interfacial structure of a styrene-d8-2-vinylpyridine diblock copolymer thin films with lamellar microdomain was investigated by neutron reflectivity (NR) measurement at different temperatures above Tg of the component polymer. The thin film specimens with different film thicknesses were prepared by spin-coating method, and then annealed at 170°C in vacuum during more than one week before NR measurement. The observed specular reflectivity profiles exhibit several Bragg peaks up to high order, implying that the lamellar structure keeps highly-ordered state and preferential orientation along the direction parallel to the film surface even at high temperature above Tg. Further, it was found that the temperature dependence of lamellar domain spacing is different according the difference in total film thickness.

AB - Interfacial structure of a styrene-d8-2-vinylpyridine diblock copolymer thin films with lamellar microdomain was investigated by neutron reflectivity (NR) measurement at different temperatures above Tg of the component polymer. The thin film specimens with different film thicknesses were prepared by spin-coating method, and then annealed at 170°C in vacuum during more than one week before NR measurement. The observed specular reflectivity profiles exhibit several Bragg peaks up to high order, implying that the lamellar structure keeps highly-ordered state and preferential orientation along the direction parallel to the film surface even at high temperature above Tg. Further, it was found that the temperature dependence of lamellar domain spacing is different according the difference in total film thickness.

UR - http://www.scopus.com/inward/record.url?scp=33645565028&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645565028&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33645565028

SP - 3281

EP - 3282

T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Temperature dependence of block copolymer thin films with different film thickness

Abstract

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All Science Journal Classification (ASJC) codes

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