Abstract
The synthesis and reactions of 3,4-benzo-1,2-disilacyclobut-3-enes and benzo[1,2:4,5]bis(1,2-disilacyclobut-3-ene)s developed by our group are reported in this review. The palladium-, platinum- and nickel-catalyzed reactions of benzodisilacyclobutenes and benzobis(disilacyclobutene)s with unsaturated compounds afford various types of products. The structures of the products are dependent upon the nature of the transition metal used as a catalyst. The reactions of cis- and trans-benzodisilacyclobutenes with alkenes and alkynes in the presence of a transition-metal catalyst proceed with high stereospecificity to give the respective adducts. The thermal reactions of cis- and trans-benzodisilacyclobutenes with various substrates also proceed stereospecifically to give adducts. The results of theoretical calculations for the platinum-catalyzed reaction of disilacyclobutene with acetylene, the nickel-catalyzed reaction of benzodisilacyclobutene and the thermal reaction of benzobis(disilacyclobutene) are discussed in this review.
| Original language | English |
|---|---|
| Pages (from-to) | 3210-3235 |
| Number of pages | 26 |
| Journal | Dalton Transactions |
| Volume | 45 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Jan 1 2016 |
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All Science Journal Classification (ASJC) codes
- Inorganic Chemistry
Cite this
The chemistry of benzodisilacyclobutenes and benzobis(disilacyclobutene)s : New development of transition-metal-catalyzed reactions, stereochemistry and theoretical studies. / Ishikawa, Mitsuo; Naka, Akinobu; Yoshizawa, Kazunari.
In: Dalton Transactions, Vol. 45, No. 8, 01.01.2016, p. 3210-3235.Research output: Contribution to journal › Review article
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TY - JOUR
T1 - The chemistry of benzodisilacyclobutenes and benzobis(disilacyclobutene)s
T2 - New development of transition-metal-catalyzed reactions, stereochemistry and theoretical studies
AU - Ishikawa, Mitsuo
AU - Naka, Akinobu
AU - Yoshizawa, Kazunari
PY - 2016/1/1
Y1 - 2016/1/1
N2 - The synthesis and reactions of 3,4-benzo-1,2-disilacyclobut-3-enes and benzo[1,2:4,5]bis(1,2-disilacyclobut-3-ene)s developed by our group are reported in this review. The palladium-, platinum- and nickel-catalyzed reactions of benzodisilacyclobutenes and benzobis(disilacyclobutene)s with unsaturated compounds afford various types of products. The structures of the products are dependent upon the nature of the transition metal used as a catalyst. The reactions of cis- and trans-benzodisilacyclobutenes with alkenes and alkynes in the presence of a transition-metal catalyst proceed with high stereospecificity to give the respective adducts. The thermal reactions of cis- and trans-benzodisilacyclobutenes with various substrates also proceed stereospecifically to give adducts. The results of theoretical calculations for the platinum-catalyzed reaction of disilacyclobutene with acetylene, the nickel-catalyzed reaction of benzodisilacyclobutene and the thermal reaction of benzobis(disilacyclobutene) are discussed in this review.
AB - The synthesis and reactions of 3,4-benzo-1,2-disilacyclobut-3-enes and benzo[1,2:4,5]bis(1,2-disilacyclobut-3-ene)s developed by our group are reported in this review. The palladium-, platinum- and nickel-catalyzed reactions of benzodisilacyclobutenes and benzobis(disilacyclobutene)s with unsaturated compounds afford various types of products. The structures of the products are dependent upon the nature of the transition metal used as a catalyst. The reactions of cis- and trans-benzodisilacyclobutenes with alkenes and alkynes in the presence of a transition-metal catalyst proceed with high stereospecificity to give the respective adducts. The thermal reactions of cis- and trans-benzodisilacyclobutenes with various substrates also proceed stereospecifically to give adducts. The results of theoretical calculations for the platinum-catalyzed reaction of disilacyclobutene with acetylene, the nickel-catalyzed reaction of benzodisilacyclobutene and the thermal reaction of benzobis(disilacyclobutene) are discussed in this review.
UR - http://www.scopus.com/inward/record.url?scp=84959191540&partnerID=8YFLogxK
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U2 - 10.1039/c5dt04569j
DO - 10.1039/c5dt04569j
M3 - Review article
VL - 45
SP - 3210
EP - 3235
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 8
ER -