The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates

Takashi Yoshikawa, Seiji Mori, Mitsuru Shindo

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

We have shown the first experimental evidence of the alkynyl substituent effect on torquoselectivity and succeeded in effecting the highly torquoselective olefination of alkynyl ketones to provide functionalized tetrasubstituted olefins.

Original languageEnglish
Pages (from-to)2092-2093
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number6
DOIs
Publication statusPublished - Feb 18 2009

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Alkenes
Ketones
Olefins

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates. / Yoshikawa, Takashi; Mori, Seiji; Shindo, Mitsuru.

In: Journal of the American Chemical Society, Vol. 131, No. 6, 18.02.2009, p. 2092-2093.

Research output: Contribution to journalArticle

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