The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates

Takashi Yoshikawa; Seiji Mori; Mitsuru Shindo

doi:10.1021/ja809592q

The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates

Takashi Yoshikawa, Seiji Mori, Mitsuru Shindo

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

We have shown the first experimental evidence of the alkynyl substituent effect on torquoselectivity and succeeded in effecting the highly torquoselective olefination of alkynyl ketones to provide functionalized tetrasubstituted olefins.

Original language	English
Pages (from-to)	2092-2093
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	6
DOIs	https://doi.org/10.1021/ja809592q
Publication status	Published - Feb 18 2009

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja809592q

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title = "The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates",

abstract = "We have shown the first experimental evidence of the alkynyl substituent effect on torquoselectivity and succeeded in effecting the highly torquoselective olefination of alkynyl ketones to provide functionalized tetrasubstituted olefins.",

author = "Takashi Yoshikawa and Seiji Mori and Mitsuru Shindo",

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doi = "10.1021/ja809592q",

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AU - Yoshikawa, Takashi

AU - Mori, Seiji

AU - Shindo, Mitsuru

PY - 2009/2/18

Y1 - 2009/2/18

N2 - We have shown the first experimental evidence of the alkynyl substituent effect on torquoselectivity and succeeded in effecting the highly torquoselective olefination of alkynyl ketones to provide functionalized tetrasubstituted olefins.

AB - We have shown the first experimental evidence of the alkynyl substituent effect on torquoselectivity and succeeded in effecting the highly torquoselective olefination of alkynyl ketones to provide functionalized tetrasubstituted olefins.

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JO - Journal of the American Chemical Society

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The effect of alkynyl groups on torquoselectivity. highly stereoselective olefination of alkynyl ketones with ynolates

Abstract

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