The effects of preparation condition and dopant on the electrochemical property for Fe-substituted Li2MnO3

Mitsuharu Tabuchi, Akiko Nakashima, Kazuaki Ado, Hikari Sakaebe, Hironori Kobayashi, Hiroyuki Kageyama, Kuniaki Tatsumi, Yo Kobayashi, Shiro Seki, Atsushi Yamanaka

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42 Citations (Scopus)

Abstract

The specific capacity of Fe-substituted Li2MnO3 (Li1.2Fe0.4Mn0.4O2) was improved by adjusting the preparation temperature of Fe-Mn co-precipitate below RT in order to suppress the spinel ferrite formation, which hinders the formation of homogeneous and reactive precursor. The degradation of discharge capacity with cycle could be suppressed by nominal 5% Al, Ni and Co doping. This means that Fe-substituted Li2MnO3 will be considered to be one of the near future positive electrodes for practical use by careful optimization of its preparation condition and chemical composition.

Original languageEnglish
Pages (from-to)287-293
Number of pages7
JournalJournal of Power Sources
Volume146
Issue number1-2
DOIs
Publication statusPublished - Aug 26 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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