The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes

Bao Li, Feng Lei Yang, Jun Tao, Osamu Sato, Rong Bin Huang, Lan Sun Zheng

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The effects of pressure on valence trautomeric transition behavior of two complexes, [{Co(tpa)}2(dhbq)]·(PF6)3 (I·(PF6)3) and [{Co(dpqa)}2(dhbq)] ·(PF6)3 (II·(PF6)3) (tpa = tris(2-pyridylmethyl)amine, dpqa = di(2-pyridylmethyl)-N-(quinolin-2- ylmethyl)amine and dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone), in the light of changes of magnetic susceptibilities were investigated; the results show that external pressure makes the SC + ET transition process of the two complexes into a general SC process only.

Original languageEnglish
Pages (from-to)6019-6021
Number of pages3
JournalChemical Communications
Issue number45
DOIs
Publication statusPublished - Dec 1 2008

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Cobalt
Amines
Magnetic susceptibility
tris(2-pyridylmethyl)amine
2,5-dihydroxy-1,4-benzoquinone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes. / Li, Bao; Yang, Feng Lei; Tao, Jun; Sato, Osamu; Huang, Rong Bin; Zheng, Lan Sun.

In: Chemical Communications, No. 45, 01.12.2008, p. 6019-6021.

Research output: Contribution to journalArticle

Li, Bao ; Yang, Feng Lei ; Tao, Jun ; Sato, Osamu ; Huang, Rong Bin ; Zheng, Lan Sun. / The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes. In: Chemical Communications. 2008 ; No. 45. pp. 6019-6021.
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