The Effects of Si and Al Alloying on α/γ Phase Equilibria in Fe-Cr-Ni-Mn Based Ternary and Quaternary Systems

I. Shuro, S. Kobayashi, T. Nakamura, Kaneaki Tsuzaki

Research output: Contribution to journalArticle

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Abstract

Phase equilibria between the ferrite phase (α) and the austenite phase (γ) were investigated in the iron-rich corner of the Fe-Cr-Mn-Ni-Si/Al systems at 1000 °C using a diffusion multiple approach and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) techniques. Cr equivalents of Si and Al are established as a function of Ni and Mn content in contrast to fixed values reported in other studies. The Cr equivalents of Si (Creq Si) are in the range between −0.5 and 1.3 being positive at 0 wt.% Mn and with values slightly below zero at 5-15 wt.% Mn. The Cr equivalents of Al (Creq Al) ranged between 0.6 and 4.8 decreasing with increase in Ni and Mn content. When compared to Creq Al, the Creq Si do not show a strong dependence on Ni and Mn content. Thermodynamic calculation using Thermo-Calc software agrees with the experimental results qualitatively.

Original languageEnglish
Pages (from-to)53-59
Number of pages7
JournalJournal of Phase Equilibria and Diffusion
Volume36
Issue number1
DOIs
Publication statusPublished - Jan 1 2014

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ternary systems
Alloying
Phase equilibria
Austenite
alloying
Ferrite
Energy dispersive spectroscopy
Iron
Thermodynamics
Scanning electron microscopy
austenite
ferrites
computer programs
iron
thermodynamics
scanning electron microscopy
spectroscopy
energy

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Metals and Alloys
  • Materials Chemistry

Cite this

The Effects of Si and Al Alloying on α/γ Phase Equilibria in Fe-Cr-Ni-Mn Based Ternary and Quaternary Systems. / Shuro, I.; Kobayashi, S.; Nakamura, T.; Tsuzaki, Kaneaki.

In: Journal of Phase Equilibria and Diffusion, Vol. 36, No. 1, 01.01.2014, p. 53-59.

Research output: Contribution to journalArticle

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AB - Phase equilibria between the ferrite phase (α) and the austenite phase (γ) were investigated in the iron-rich corner of the Fe-Cr-Mn-Ni-Si/Al systems at 1000 °C using a diffusion multiple approach and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) techniques. Cr equivalents of Si and Al are established as a function of Ni and Mn content in contrast to fixed values reported in other studies. The Cr equivalents of Si (Creq Si) are in the range between −0.5 and 1.3 being positive at 0 wt.% Mn and with values slightly below zero at 5-15 wt.% Mn. The Cr equivalents of Al (Creq Al) ranged between 0.6 and 4.8 decreasing with increase in Ni and Mn content. When compared to Creq Al, the Creq Si do not show a strong dependence on Ni and Mn content. Thermodynamic calculation using Thermo-Calc software agrees with the experimental results qualitatively.

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