The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Mitsuru Shindo, Kenji Matsumoto, Seiji Mori, Kozo Shishido

Research output: Contribution to journalArticlepeer-review

77 Citations (Scopus)

Abstract

We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

Original languageEnglish
Pages (from-to)6840-6841
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number24
DOIs
Publication statusPublished - Jun 19 2002
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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