The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity

Shintaro Kawamura, Kentaro Ishizuka, Hikaru Takaya, Masaharu Nakamura

Research output: Contribution to journalArticle

58 Citations (Scopus)

Abstract

The first example of an iron-catalysed Negishi coupling between arylaluminium reagents and alkyl halides illustrates that the co-existing salts highly influence the dynamic equilibrium of the organoaluminium species, and have a critical effect on the reactivity and selectivity of the coupling reaction.

Original languageEnglish
Pages (from-to)6054-6056
Number of pages3
JournalChemical Communications
Volume46
Issue number33
DOIs
Publication statusPublished - Sep 7 2010

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint Dive into the research topics of 'The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity'. Together they form a unique fingerprint.

  • Cite this