The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity

Shintaro Kawamura, Kentaro Ishizuka, Hikaru Takaya, Masaharu Nakamura

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

The first example of an iron-catalysed Negishi coupling between arylaluminium reagents and alkyl halides illustrates that the co-existing salts highly influence the dynamic equilibrium of the organoaluminium species, and have a critical effect on the reactivity and selectivity of the coupling reaction.

Original languageEnglish
Pages (from-to)6054-6056
Number of pages3
JournalChemical Communications
Volume46
Issue number33
DOIs
Publication statusPublished - Sep 7 2010
Externally publishedYes

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Aluminum
Iron
Salts

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

The first iron-catalysed aluminium-variant Negishi coupling : Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity. / Kawamura, Shintaro; Ishizuka, Kentaro; Takaya, Hikaru; Nakamura, Masaharu.

In: Chemical Communications, Vol. 46, No. 33, 07.09.2010, p. 6054-6056.

Research output: Contribution to journalArticle

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